Mark Bishop

Analytical Chemistry and

Signal Acquisition/Analysis



Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
Introduction
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Introduction


Alkenes

Preparation

Dehydrohalogenation of alkyl halides

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Dehydration of alcohols

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Mechanism

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Dehalogenation of vicinal dihalides

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Reduction of alkynes

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Reactions

Addition reactions

Hydrogenation

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Halogenation

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Hydrohalogenation

Electrophillic addition yields Markovnikov stereochemistry. Peroxide presence yields anti-Markovnikov products by free radical addition. Markovnikov's rule: Electrophilic addition to a C-C double bond involves the formation of the more stable carbocation. (In ionic addition of an acid to a carbon-carbon double bond, the hydrogen attaches itself to the carbon that already holds the greater number of hydrogens).

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Addition of sulfuric acid

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Hydration

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Halohydrin formation

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Glycol formation

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Alkylation

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Oxymercuration - demurcuration

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Hydroboration- oxidation

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Free Radical Addition

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Glycol formation

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Allylic substitution

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Cleavage Reactions

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